Microwave spectrum, structure, and dipole moment of 3,3‐difluorocyclopropene

Abstract

The microwave spectra of four isotopic species of 3,3‐difluorocyclopropene have been investigated in the region from 18–40 GHz. Structural parameters obtained are r (C1C2) =1.321±0.001, r (C1C3) =1.438±0.007, r (CH) =1.075±0.001 , r (CF) =1.365±0.005 Å, &FCF=105.5±0.5°, &C1C3C2=54.6±0.4°, &HC1C2=148.4±0.1°. From the Stark effect the dipole moment has been determined to be 2.98±0.02 D.

Publisher

AIP Publishing

Publication Date

1-1-1976

Publication Title

Journal of Chemical Physics

Department

Chemistry and Biochemistry

Document Type

Article

DOI

https://dx.doi.org/10.1063/1.432138

Keywords

Electric dipole moments, Microwave spectra, Stark effect

Language

English

Format

text

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