A Reassignment of the Vibrational Fundamentals of Sulfuryl Chloride Fluoride

Authors

Norman C. Craig, Oberlin College
Kenichi Futamura

Abstract

Low temperature Raman spectroscopy has led to a significant revision in the assignment of the vibrational fundamentals of sulfuryl chloride fluoride (SO2FCl). The fundamentals in cm−1 are: (a′) 1230, 826, 632, 503, 422, 295; (a″) 1469, 476, 303. All are from gas-phase i.r. spectra except 295 cm−1, which is from the liquid-phase Raman spectrum. The revised assignments are consistent with the predictions of Pfeiffer's normal coordinate calculations [Z. phys. chem., Leipzig 240, 380 (1969)].

Repository Citation

Craig, Norman C. and Kenichi Futamura. 1989. "A Reassignment of the Vibrational Fundamentals of Sulfuryl Chloride Fluoride." Spectrochimica Acta Part A: Molecular Spectroscopy 45(4): 507-509.

Publisher

Elsevier BV

Publication Date

1-1-1989

Publication Title

Spectrochimica Acta Part A: Molecular Spectroscopy

Department

Chemistry and Biochemistry

Document Type

Article

DOI

https://dx.doi.org/10.1016/0584-8539(89)80049-2

Language

English

Format

text